Abstract
Abstract Synthesis and X-ray structure analyses were carried out for fac-cis-[MnCl(CO)3dppfe] and fac-cis-[MnH(CO)3dppfe], and a cyclic voltammetric study was made for a series of manganese carbonyl derivatives with 1,1′-bis(diphenylphosphino)ferrocene (dppfe), including these new compounds. Unusually a low oxidation potential for the Mn site is revealed for [Mn(MeCp)(CO)dppfe]. A good correlation between ν(CO) and the oxidation potential for the Mn atom has been clarified.
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