Synthesis, thermodynamic properties and antibacterial activities of lanthanide complexes with 3,5-dimethoxybenzoic acid and 1,10-phenanthroline

Abstract

Four lanthanide complexes with a general formula [Ln(3,5-DmeoxBA)3(phen)]2 (Ln=Tb(1), Dy(2), Er(3), Yb(4); 3,5-DmeoxBA=3,5-dimethoxybenzoic acid; phen=1,10-phenanthroline) were synthesized and characterized by elemental analysis, infrared spectra (IR), and thermogravimetric, differential scanning calorimetry techniques, combined with Fourier transform infrared (TG/DSC–FTIR) technology. The thermal decomposition processes of the four complexes were investigated by TG/DSC–FTIR techniques. Heat capacities were measured by DSC. The values of the experimental heat capacities were fitted to a polynomial equation with the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions (HT−H298.15K), (ST−S298.15K), and (GT−G298.15K) were calculated. The antibacterial action of the four complexes on bacteria and fungus such as Escherichia coli, Staphylococcus aureus and Candida albicans were studied by filter paper approach. The luminescent properties of the complexes 1 and 2 were also studied.