Abstract
A novel hydrogen bonded supramolecular single crystals of 4-methoxyanilinium perchlorate (4MAPC) has been synthesized by solvent slow evaporation method. Structural and crystallographic data of 4MAPC has been studied by single crystal XRD technique. Three dimensional networks formed by the classical hydrogen bond between nitrogen and oxygen and also the nonclassical intermolecular interaction between carbon and oxygen keeping the crystal structure more stable. Protonation is observed at nitrogen site of 4-methoxyaniline from the perchloric acid. The results of thermal gravimetric and differential themal analysis showed that the grown crystal is stable upto 167 °C. The wide transparency from 340 to 1100 nm was observed by optical studies. The high nonlinear optical susceptibility and nonlinear refraction was obtained from Z-Scan studies.
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