Abstract

A novel coordination complex [Cu 2L(4,4′-bpy)(H 2O)](ClO 4) 4 · 3H 2O was synthesized by treatment of Cu(ClO 4) 2 · 6H 2O and 4,4′-bipyridine (4,4′-bpy) with a macrocyclic multidentate ligand L containing two diethylenetriamine units as coordination moieties and two biphenylene groups as rigid spacers. The compound was characterized by X-ray crystallography, electrospray mass spectroscopy (ES-MS), and its magnetic property was studied.

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