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Abstract
A 1-D metal-isonicotinato inorganic–organic hybrid complex [Gd(C6NO2H5)3(H2O)2]2 n · (nH5O2)(nZnCl5)(2nZnCl4) · (2nH2O) (1) has been synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 is a 1-D polycationic chain-like structure with unprecedented . Optical absorption spectra of 1 reveal the presence of an optical gap of 3.35 eV. Photoluminescence investigations reveal that the complex 2 display a strong blue-light fluorescent emission band.
Published Version
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