Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with 1,5-dinitronaphthalene-3,7-dicarboxylate

Abstract

Two new metal–organic coordination polymers with 1,5-dinitronaphthalene-3,7-dicarboxylate (NNDC), [Cu 2(NNDC) 2(DMF) 1.8(DMSO) 2.2(H 2O) 2]·H 2O (1) and [Mn 3(NNDC) 3(DMSO) 4]·2DMSO (2) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and Thermogravimetric Analysis (TGA). The structure of compound 1 consists of one-dimensional chains with copper ions being linked by the dicarboxylate ligands. The coordination chains are associated into ladder-like double chains through O–H⋯O hydrogen bonds and π–π interactions, and the ladders are packed in a cross fashion through further π–π interactions to give the three-dimensional structure. The Mn(II) compound exhibits a 3D framework with the pcu topology, in which [Mn 3(COO) 6] clusters as octahedral secondary building blocks are linked by the naphthalene spacers. Magnetic analyses were carried out based on both temperature- and field-dependent data, consistently suggesting relatively weak antiferromagnetic interactions within the carboxylate bridged [Mn 3(COO) 6] cluster.