Abstract

Some of 9-aryl-9,10-dihydro-9-silaanthracenes ( 1) were prepared and the alkylation of the compounds gave trans-9-aryl-10-alkyl-9,10-dihydro-9-silaanthracenes exclusively. Upon photolysis of a 9-phenyl derivative, 9-phenyl-9-silaanthracene was confirmed by spectroscopic analysis. Also, structural studies of the dihydro compounds were performed by NMR and X-ray.

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