Abstract

Abstract The reaction of [(η6-C6Me6)RuCl2]2 with excess BH3·THF produced a ruthenaborane cluster, arachno-[(η6-C6Me6)RuB4H10] (1). Compound 1 underwent cluster degradation through the action of Pme3 to afford arachno-[(η6-C6Me6)Ru(Pme3)B3H7] (2).

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