Abstract
An eight-nuclear complex, {[Ni(tacn) 2] 5[Cr(CN) 6] 3}ClO 4 · 18.5H 2O (tacn = 1, 4, 7-triazacyclononane), connected by 18.5 water molecules has been synthesized and characterized structurally and exhibits weak ferromagnetic interactions. This complex consists of a 3D structure with 1D metal–water chain containing planar hexacyclic water rings.
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