Abstract
Two 3D isostructural Co/Mn (II) metal organic frameworks (MOFs), namely, {[Co(BIPA-TC4-)0.5(bpbp)]·2MeCN}n (1) and {[Mn(BIPA-TC4-)0.5(bpbp)]}n (2). (H4BIPA-TC = 5,5′-(1,3,6,8-tetraoxybenzo [3], [8] phenanthroline 2–7-substituent)bis-1,3-benzoic acid and bpbp = 4,4′-bis(Pyrid-4-yl)biphenyl) have been solvothermally constructed based on H4BIPA-TC ligand and cobalt or manganese salts. And two Co/Mn (II) MOFs were further characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, thermogravimetric analysis and powder X-ray diffraction experiments. The structure analysis showed 1 and 2 are isostructural 3D networks with a Schläfli symbol of {44.610.8} {44.62}. Moreover, magnetic properties of 1 and 2 were also investigated.
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