Abstract

AbstractTwo types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand ‐ diphenyl‐(1‐propylbenzimidazol‐2‐yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.

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