Abstract
The new cobalt(II) coordination polymer [Co(bim)2(dca)2] n (1), (bim = benzimidazole, dca = dicyanamide) was synthesized and characterized. X-ray diffraction analyses reveal that the title complex crystallizes in the monoclinic space group P21/n with a = 9.168(5), b = 9.959(5), c = 9.850(5) A, β = 105.360(11)o, Z = 2, and R 1 = 0.0308, wR 2 = 0.0728. The coordination geometry of cobalt atom is distorted octahedral, coordinated equatorially by four nitrogen atoms from four dicyanamide ligands, and axially by two nitrogen atoms from two benzimidazole molecules. Each dca ligand links two cobalt(II) atoms and 1 forms a two-dimensional (4,4) network. The spectroscopic and magnetic properties have also been investigated. The new cobalt(II) coordination polymer [Co(bim)2(dca)2] n (1), (bim = benzimidazole, dca = dicyanamide) was synthesized and characterized by X-ray diffraction analyses. The coordination geometry of cobalt atom is distorted octahedral, coordinated equatorially by four nitrogen atoms from four dicyanamide ligands, and axially by two nitrogen atoms from two benzoimidazole molecules. Each dca ligand links two cobalt(II) atoms and 1 forms a two-dimensional (4,4) network. The spectroscopic and magnetic properties have also been investigated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
