Abstract
The hydrothermal synthesis, structure and magnetic studies of a one-dimensional iron fluro-phosphate, [NH 3 CH 2 CH 2 CH(NH 3 )CH 2 CH 3 ] 2+ ∝ 1 [FeF(HPO 4 ) 2 ] 2− , I, is presented. The structure, solved by single-crystal X-ray diffraction, consists of isolated 1 ∝[FeF(HPO 4) 2] 2− chains of the tancoite type with diprotonated amine molecules situated in between. Magnetic studies indicate anti-ferromagnetic interactions. Crystal data: space group= P2 1/ m (no. 12), a=8.846(2) Å, b=7.211(1) Å, c=9.893(2) Å, β=97.10(3)°, V=626.2(2) Å 3, Z=4, ρ calc=1.968 g cm −3, μ(Mo Kα)=1.511 mm −1, R 1=0.044, w R 2=0.099, S=1.016 for 134 parameters.
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