Abstract
Two novel ZnII complexes based on a tripodal carboxamide-containing ligand, [Formula: see text] and [Formula: see text] (where LL-2 = N′, N″, N′″-tris(pyrid-2-ylmethyl)-1,3,5-benzenetricarboxamide) are synthesized and structurally characterized. The first complex is a zero-dimensional structure which was further connected into a three-dimensional structure via hydrogen bond interactions, while the second complex features a one-dimensional tube-like structure, where the structural diversities were mainly caused by the different anions. The solid-state luminescent properties of the complexes were investigated and powder X-ray diffraction and thermal gravimetric analysis were performed.
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