Abstract
The title compound has been synthesized from molybdenum(VI) oxide and ammonium vanadate in aqueous solution by adding morpholine (pH 5.8). The X-ray structural investigation shows that the polyoxometalate anion adopts a Keggin-type structure with a central tetrahedral vanadium(V) atom. The other two vanadium atoms are crystallographically disordered over 12MO 6 octahedral sites. The ESR spectrum clearly indicates that one octahedrally coordinated vanadium atom has the oxidation number +4.
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