Abstract

Syntheses of chiral sulfide complexes [(η 5 -C 5 H 5 )Re(NO) (L)(SRR')] + X − (L=PPh 3 , CO), dynamic NMR studies that establish some of the lowest known sulfur inversion barriers, crystal structures of two dimethyl sulfide complexes, and preliminary studies, including a crystal structure, of analogous sulfoxide complexes

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