Abstract

A series of Ba1-xSrxMyTi1-yO3 (M = Zr, Sn, 0⩽x⩽0.4, 0⩽y⩽0.3) solid solutions were synthesized with the soft chemical method below 100 °C. XRD pattern and cell parameters-composition figures of the prepared powder demonstrate that they are completely miscible solid solutions based on BaTiO3. Furthermore, TEM shows that they have a shape of uniform, substantially spherical particles with an average particle size of 70 nm in diameter. The sintered ceramics of the powder doped with Sr2+and Zr4+ or Sn4+ have dielectric constant eight times higher and dielectric loss thirty per cent lower than those of pure BaTiO3 phase at room temperature.

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