Abstract
A new molybdenum(VI) complex, [MoO2(CH3OH)(L)] (L = N′-(4-diethylamino-2-hydroxybenzylidene)-4-hydroxybenzohydrazide), was prepared and characterized by spectroscopy methods and single crystal X-ray diffraction (CIF file CCDC no. 1038153). The crystal of the complex, C19H23MoN3O6, crystallizes in the triclinic space group \(P\bar 1\) with unit cell dimensions a = 6.9824(9), b = 10.206(1), c = 15.302(2) A, α = 94.399(2)°, β = 101.877(2)°, γ = 104.062(2)°, V = 1025.9(2) A3, Z = 2, R1 = 0.0317, wR2 = 0.0796, S = 1.060. The Mo atom in the complex is in an octahedral coordination with phenolate O, imino N, enolate O atoms of the ligand L, and one oxo O in the equatorial plane, and with one methanol O and the other oxo O in the axial sites. Crystals of the complex are stabilized by hydrogen bonds. The complex was studied for its catalytic oxidation property on some olefins, with tert-butyl hydrogen peroxide as oxidant.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
