Abstract
Abstract The new violet oxorhenium(V) complex ReOCl3(pinacop) {pinacop = (OCMe2CMe2O)POCMe2CMe2OP (OCMe2CMe2O)} was obtained by reaction of ReOCl3(OPPh3)(SMe2) with a stoichiometric amount of pinacop. Facial geometry was determined by spectroscopic means and preliminary results from an X-ray crystallographic study. The catalytic properties of the title compound in oxygen atom transfer reactions are discussed.
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