Abstract
Two new copper(II) complexes were synthesized from 2-hydroxyl-4-methoxyacetophone with R-NH–CH2–CH2–CH2–NH2 (for complex 1, R = H; complex 2, R = C6H5–CH2–) in the presence of Cu2+. Crystals of 1 were monoclinic, space group P21/n, with a = 12.6408(10) Å, b = 7.4063(6) Å, c = 16.8863(14) Å and β = 93.3590(10)°, complex 2 crystals were triclinic, space group P with a = 7.561(3) Å, b = 10.680(4) Å, c = 13.868(5) Å and α = 97.389(6)°, β = 95.240(6)°, γ = 101.206(6)°. Both Cu(II) atoms were four-coordinate with distorted square-planar geometry. The toxicity of 1 and 2 were evaluated by testing antimicrobial activity against bacterial strands.
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