Abstract
The aim of this review paper is to provide the compact overview of experimental synthesis route, crystallography of perovskite (ABO3) hexagonal polytypes and their related physical properties. Structural stacking sequence of the oxygen deficient hexagonal perovskite oxides (ABO3-δ) is briefly discussed. The fundamental aspects of magnetic and electrical properties involved in hexagonal polytypes are elaborated using reported systems. The magnetic field induced effect such as magnetocaloric effect, magnetoresistance and magneto-dielectric effect in perovskite hexagonal polytypes are also discussed for their possible application in magnetic refrigeration, magnetic sensors and memory devices.
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