Synthesis, structural and optical properties of ZnO and Ni-doped ZnO hexagonal nanorods by Co-precipitation method

Abstract

Ni doped ZnO (Zn1−xNixO, x=0.0, 0.03, 0.06 and 0.09) nanorods have been synthesized by Co-precipitation method. Zinc acetate dehydrate [Zn(CH3COO)2⋅2H2O], nickel nitrate [Ni(NO3)3⋅6H2O], sodium hydroxide and poly (vinyl pyrrolidone) (PVP) were mixed together. The morphology, optical and microstructure were determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy dispersive spectrum (EDS), atomic force microscopy (AFM), UV-DRS spectrum, photoluminescence spectra (PL) and Fourier transformer infrared spectroscopy (FT-IR). The presence of functional groups and chemical bonding is confirmed by FTIR. PL spectra of the Zn1−xNixO systems shows that the shift in near band edge (NBE) UV emission from 321 to 322nm and a shift in red band (RB) emission from 620 to 631nm which conforms the substitution of Ni into the ZnO lattice. The investigation conformed that the products were of the wurtzite structure of ZnO. The hexagonal nanorods have edge length 31nm and thickness of 39nm. EDS result showed that the amount of Ni in the product is about 9%, these Ni doped hexagonal nanorods exhibits a blue shifts and weak (UV) emission peak, compared with pure ZnO, which may be induced by the Ni-doping different concentrations 0.0, 0.3, 0.6 and 0.9M. The growth mechanism of the doped hexagonal nanorods was also discussed.