Abstract

Eu2+ and Dy3+ singly doped and codoped GdAlO3 phosphor was synthesized by solid state reaction method in a reducing atmosphere of nitrogen. Samples were characterized by powder X-ray diffraction (PXRD) analysis. The average crystal size was obtained around 68 nm. Surface morphology was verified by scanning electron microscopy (SEM) analysis. The emission spectra of phosphors singly doped with Eu2+ and codoped with Eu2+; Dy3+ respectively were recorded under 354 nm excitation. The emission spectra of Eu2+ has intense emission peak at 515 nm. It was observed that the after codoping with Eu2+ and Dy3+ the emission bands of Eu2+ dominates along with a new emission band centred at 419 nm. CIE chromaticity diagram shows variation in emitted colour with Eu2+, Dy3+ singly doped and codoped phosphor. The investigation of Dy3+ codoping shows the colour tunable behaviour of the phosphor. This colour tunable behaviour of the phosphor makes it useful in the colour display applications.

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