Synthesis, spectroscopy, band gap energy and electrical conductivity of poly(dopamine–co–aniline) copolymer

Abstract

Copolymerization is used to improve the solubility and processability of polymers and copolymers includes the individual properties of homopolymer. In this study, the poly(dopamine-co-aniline) (poly(DA-co-ANI) copolymer was synthesized and the UV–vis. absorption, optical band gap energy, fluorescence, FT-IR, SEM-EDS, MALDI-TOF-MS, XRD and electrical conductivity have been investigated. The obtained results for the poly(DA-co-ANI) copolymer were compared with the PDA and PANI homopolymers. It was observed that the poly(DA-co-ANI copolymer is soluble easily in NMP and DMF solvents. The optical band gap energy of the poly(DA-co-ANI) copolymer film were calculated. as 1.00 eV with favorable indirect transition. The poly(DA-co-ANI) copolymer showed the FL emission maximum bands at 390 and 533 nm wavelengths. It was observed from the SEM images that the poly(DA-co-ANI) has 0–1500 nm crystalline rectangular particles prepared in acidic media and 0–600 nm amorphous particles prepared in basic media. The electrical conductivity of the poly(DA-co-ANI) was 1.35 × 10−6 S/cm. In the MALDI-TOF-MS measurements, the number-average molecular weight of the copolymer was found as 2628 Da with a distribution up to 5500 Da. The poly(DA-co-ANI) copolymer, soluble in NMP and DMF solvents and with a low optical band gap energy can be utilized as optical, fluorescent, and semi-conductive material in biomedical applications.