Abstract
The redox chemistry of chromium(VI) is presented with respect to the final products of the interaction of K 2CrO 4 with main cellular reductants. The isolation of a family of chromium(III) complexes obtained from the reduction of the chromate ion with ascorbic acid, crysteine and glutathione is described. The compounds have been characterized by elemental, IR and electronic spectroscopy and magnetic measurements. All complexes exhibit a tetragonal deformation around chromium(III) with the MO 4XX′ chromophore (X,X′—O′,S,N).
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