Synthesis, Spectral, and Biocidal Studies of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Mixed‐Ligand Complexes

Abstract

Complexes of transition metals with salicylaldehyde (salH) or 5‐bromo‐salicylaldehyde (Br‐salH) in 1:2 molar ratio, have the compositions [M(H2O)2(sal)2] · H2O (1) or [M(H2O)2(Br‐sal)2] · H2O (2), respectively. The Schiff base derived from ethylenediamine and acetophenone in 1:1 molar ratio in alcoholic solution yields bis(acetophenone)ethylenediamine (acphen). Further reaction of (1) or (2) with acphen in alcohol yielded mixed‐ligand complexes of the type [M(sal)2acphen] or [M(Br‐sal)2 acphen], respectively. All of these complexes are soluble in ethanol and methanol. They were characterized on the basis of elemental analyses, magnetic measurements, infrared spectra, electronic spectra, and thermogravimetric analyses. All of these complexes have been screened for their antimicrobial activity against bacterial strands using the agar diffusion method.