Abstract

Three new 2-picolyloxy lariat ether compounds are prepared and solid-state structures are determined for two of them. Complexation behavior for a series of lariat ethers with pyridyl-containing side arms toward alkali metal cations and Ag + is assessed by two-phase metal picrate extraction from aqueous solutions into chloroform and in homogeneous solutions by isothermal titration calorimetry in methanol.

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