Abstract

设计合成了含有嘧啶环的新型棒-线状N^C^N三齿配体 1 以及其二价铂配合物 1-Pt .通过核磁共振谱、基质辅助激光解析电离飞行时间质谱(MALDI-TOF mass)、场发射扫描电镜(FE-SEM)、紫外、荧光光谱等对其结构、溶液中的自组装和光谱性能进行了表征和测定.结果表明,所制备的 1-Pt 分子由于具有独特的棒-线结构,分子间容易发生π-π堆积作用,在有机溶剂中显示了良好的自组装性能,并引起荧光性能的变化.

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