Abstract
The compound [Re(CO)3(PPh3)2Cl] reacts with the lithium salt of thiazole derivatives (L1H = 2-amino-benzothiazole, L2H = 2−N-methyl-aminothiazole, L3H = 2−N-phenylaminothiazole, L4H = 2−N-(4-methoxyphenyl)aminothiazole, L5H = 2−N(4-nitrophenyl)aminothiazole) to give [Re(CO)2-(PPh3)2(L)]. The compounds have been characterized by elemental analysis, i.r. and1H n.m.r. spectra. At room temperature [Re(CO)2(PPh3)(L2)] reacts with L6H (L6H = diphenylacetic acid), to give the carboxylato complex [Re(CO)2 .
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