Abstract

The synthesis and characterization of EU-12, a novel thermally stable high-silica zeolite, are described. Sorption measurements indicate that access to the zeolitic void space is through windows with a free diameter of ∼ 0.40 nm. Ion exchange gives a hydrogen form that shows preferential formation of ethene in methanol conversion and the selective formation of cis-but-2-ene in but-1-ene isomerization.

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