Abstract
The synthesis of a new ionic liquid-type monomer has been performed by association of a methacrylate polymerizable group, a polar tri(ethylene oxide) (TEO) spacer, a trifluoromethane sulfonic (TFSI −) anion and a free imidazolium (EMIm +) cation. The ionic liquid monomer (ILM) has demonstrated a good thermal stability and a high ionic conductivity around 2.1 × 10 −3 S cm −1 at 20 °C. The corresponding homopolymer has shown an ionic conductivity closely related to the monomer (6.5 × 10 −4 S cm −1 at 20 °C), which confirms the ILM as a valuable monomer for the formation of polymeric ionic liquid (PIL) materials.
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