Abstract
Reaction of [Os VI(N)Cl 4] − with bis(diphenylarsino)ethane (AsAs) in acetone gave [Os VI(N)Cl 3(AsAs)] isolated as an orange solid. The complex (space group P 1 (No.2), a=11.512(2), b=14.389(2), c=19.138(4) Å, α=102.97(1), β=94.84(2), γ=110.24(1)°, V=2852.6(9) Å 3, Z=4; R=0.062 for 5216 observed Mo Kα data) is a distorted octahedral with three chlorine atoms in a meridional configuration. The measured OsN distances of the two crystallographically independent [Os VI(N)Cl 3(AsAs)] molecules are 1.70(1) and 1.66(2) Å. The photoluminescent properties of the osmium complex are discussed.
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