Synthesis of ZSM-5 zeolite from lignite fly ash and rice husk ash

Abstract

The lignite fly ash from the Mae-Moh power plant, Thailand, and rice husk ash were used as raw materials for ZSM-5 zeolite synthesis. Factors affecting the yield of ZSM-5 zeolite synthesized from fly ash, i.e., the SiO 2/Al 2O 3 mole ratio, the presence of tetrapropyl ammonium bromide (TPABr, the structure-directing material for ZSM-5 zeolite synthesis), the holding temperature and time, and the initial pressure were investigated. It was found that without TPABr only zeolite P could be synthesized at SiO 2/Al 2O 3 mole ratios of 2.8–200. In order to synthesize ZSM-5 zeolite, sodium silicate solution was added to adjust the SiO 2/Al 2O 3 mole ratio in raw ash. The yield of ZSM-5 zeolite was as high as 59 wt.% when following conditions were used: SiO 2/Al 2O 3 mole ratio, 40; the holding temperature, 210 °C; the holding time, 4 h and the initial pressure, 4 bar. The catalytic performance for CO 2 hydrogenation reaction of the ZSM-5 zeolite was preliminary tested and compared with that of commercial one. It was observed that there was no significant difference in the catalytic performance between these two catalysts.