Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene

Ilya E Nifant’Ev,Alexander A Vinogradov,Alexey A Vinogradov,Andrei V Churakov,Pavel V Ivchenko

doi:10.1016/j.mencom.2018.09.004

Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene

Ilya E Nifant’Ev, Alexander A Vinogradov + Show 3 more

https://doi.org/10.1016/j.mencom.2018.09.004

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Journal: Mendeleev Communications	Publication Date: Sep 1, 2018
Citations: 9

Affiliation: Lomonosov Moscow State University, A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, NS Kurnakova Institute of General and Inorganic Chemistry

#Synthesis Of Zirconium #X-ray Analysis + Show 8 more

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Abstract

ansa-Complex O[SiMe2(η5-C5H4)]2ZrCl2 upon reduction with LiAlH4 in contrast to zirconocene dichloride forms a dia-magnetic ZrIII complex with the dimeric molecular structure proved by X-ray analysis. This complex after activation by MeAlO initiates oligomerization of α-olefins.

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