Abstract
In connection with our investigation on the structure-activity relationships of the American cockroach sex pheromone mimic, (+)-trans-verbenyl acetate, a number of alcohols having 6,6-dimethylbicyclo[3, 1. l]heptane skeleton were synthesized, and measured their PMR spectra in the presence of the shift reagent, Eu(dpm)3. The induced shifts of the 6, 6-gem-dimethyl protons and α-proton at the C–7 guided us to distinction between cis- and trans-alcohol. The configuration of secondary methyl groups was discussed from the induced shift values of the methyl protons.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
