Abstract
A method has been developed for the regioselective synthesis of unsaturated tertiary amines via the reaction of magnesium amides, derived from Schiff bases, with allylic electrophiles in the presence of Pd and Cu complexes. The reaction of ketimines which have been metallated using magnesium amide with functionalized allylic compounds is catalyzed by Pd complexes and leads to the formation of α-allyl substituted ketones with high regioselectivity.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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