Synthesis of two cationic Coordination polymers for the exploration of anion exchange properties

Abstract

Anion exchange materials are important for their application in toxic anion control process. Coordination Polymers (CPs) with weakly coordinated anions and lattice anions may be practically useful in anion exchange process. To explore this anion exchange properties by Coordination Polymers (CPs) we have synthesized two water insoluble cationic CPs {[Mn(bix)3(H2O)2].bix.(NO3)2}n(1), {[Cd(bix)2(NO3)2].(H2O)2}n(2) by using N,N-donors linkers bix {bix = 1,4-bis(imidazol-1-ylmethyl)- benzene}. Structure of complex 1 is 1D and contains lattice NO3– anion and the complex 2 is 2D and contains weakly coordinated NO3–anion. Both these complexes along with another previously published structurally similar CP {[Cd(bix)2(NO3)2]}n (3), response in anion exchange studies with foreign anions. All the anion exchange processes have been monitored by FT-IR spectroscopy and PXRD measurements.