Abstract

30-Electron triple-decker complexes [(η-C5H5)Fe(μ-η:η-C4Me4P)Fe(η-C5Me5)]PF6 and [(η-C4Me4)Co(μ-η:η-C4Me4P)Fe(η-C5Me5)]PF6 with a central tetramethylphospholyl ligand were synthesized by stacking reactions of cationic fragments [(η-C5H5)Fe]+ and [(η-C4Me4)Co]+ with nonamethylphosphaferrocene (η-C4Me4P)Fe(η-C5Me5).

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