Abstract
Black TiO2 is capable to absorb the entire or part of the visible spectrum improving, a priori, the photoactivity under solar irradiation. Nevertheless, black TiO2 materials have not been able to demonstrate the expected photocatalytic activity in visible light due to the presence of a large number of recombination centers. In addition, high temperatures or pressures (>400 °C, 20 bar) are required for the conventional synthesis and alternative methods have high energy costs which limit the capability for mass production. In this report, a novel controlled hydrolysis method has been developed to synthesize reduced black TiO2 in mild conditions of temperature (180 °C) and pressure (8 bar). The synergetic effect of the stabilization of small crystal sizes, strong visible light absorption, band gap narrowing, Ti3+ defects or oxygen vacancies concentration, improved surface area and pollutant-surface interactions, significantly enhances the photocatalytic activity in the degradation of organic pollutants (Orange G) under visible light (almost totally degraded at 40 min).
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