Synthesis of Thin-Film Metal Pyrites by an Atomic Layer Deposition Approach.

Abstract

Late 3d transition metal disulfides (MS2 , M=Fe, Co, Ni, Cu, Zn) can crystallize in an interesting cubic-pyrite structure, in which all the metal cations are in a low-spin electronic configuration with progressive increase of the eg electrons for M=Fe-Zn. These metal pyrite compounds exhibit very diverse and intriguing electrical and magnetic properties, which have stimulated considerable attention for various applications, especially in cutting-edge energy conversion and storage technologies. The synthesis of the metal pyrites is certainly very important, because highly controllable, reproducible, and reliable synthesis methods are virtually essential for both fundamental materials research and practical engineering. In this Concept, a new approach of (plasma-assisted) atomic layer deposition (ALD) to synthesize the thin-film metal pyrites (FeS2 , CoS2 , NiS2 ) is introduced. The ALD synthesis approach allows for atomic-precision control over film composition and thickness, excellent film uniformity and conformality, and superior process reproducibility, and therefore it is of high promise for uniformly conformal metal pyrite thin-film coatings on complex 3D structures in general. Details and implications of this ALD approach are discussed in this Concept, mainly from a conceptual perspective, and it is envisioned that, with this new ALD synthesis approach, a significant amount of new studies will be enabled on both the fundamentals, and novel applications of the metal pyrite materials.