Year-end Sale % OFF 
Abstract
AbstractThe novel, low‐melting‐point (19 °C) salt [N‐pentylpyridinium]+ [closo‐CB11H12]− (2) was synthesized in 93% yield and characterized by elemental analysis, IR spectroscopy, and 1H, 13C, and 11B NMR spectroscopy. The salt was used as a solvent in several dehalogenation reactions of mono‐ and poly‐chlorides and ‐bromides, catalyzed by the palladium complexes PdCl2(PPh3)2, PdCl2(dppe), and PdCl2(dppf). Complete debromination of C6Br6, 1,2,4,5‐tetrabromobenzene, C60Br8, and C60Br24 was accomplished quite rapidly, whereas dechlorination of 1,2,4‐trichlorobenzene proceeded more slowly, but with excellent products selectivity. Copyright © 2003 John Wiley & Sons, Ltd.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
