Abstract

AbstractThe L‐acid (C1–C18) fragment of pamamycin‐593 and de‐N‐methylpamamycin‐579, strong aerial mycelium‐inducers of Streptomyces alboniger, was synthesized using a cis‐selective iodoetherification and a nucleophilic addition of a cerium acetylide to an aldehyde as the key steps. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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