Abstract

The synthesis is reported of the possible metastatic inhibitors — methyl β-d-galactopyranosyl-(1 → 4)-(2-acetamido-2-deoxy- α- d-glucopyranosyl)-(1 → 6)- β-d-galactopyranosyl-(1 → 4)- β-d-glucopyranoside ( 11) and methyl β-d- galactopyranosyl-(1 → 4)-(2-acetamido-2-deoxy- β-d- glucopyranosyl)-(1 → 6)- β-d-galactopyranosyl-(1 → 4)- β- d-glucopyranoside ( 14) — by procedures for regio- and stereo- selective coupling, reduction of azido groups, N-acetylation, and O-deacetylation.

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