Abstract
Abstract 1,4-Dichlorobuta-1,3-diene has been lithiated and reacted with organosilyl and tin chlorides. Only polymerized starting material, rather than the hoped for parent sila- and stannacyclopentadienyl (silole and stannole) ring systems result from the action of the 1ithiated material on diorganodichlorosilanes and diorganotin di-chlorides. Addition of the 1ithiated butadiene to trimethylchloro-silane and trimethyltin chloride yields products resulting from dehydrochlorination and multiple bond migration in the starting dichlorobutadiene.
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