Abstract
The one pot synthesis of Tetrahydroquinolines can be achieved by reaction of aromatic amines and formaldehyde with a variety of electron rich alkenes including styrenes and enol ethers. The cyclisation is multi-step as evidenced by the isolation of intermediates, which can be cyclised to give the @Tetrahydroquinolines, and by the observation of side-products such as oxazines, and in the case of o-phenylenediamine, the interesting tricycle ( 4)
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