Abstract
Systematic work, in Italy, on the synthesis of polymers having tertiary amino groups as structural units is reported. The polymers carry amino groups, (a) situated in the molecular main chain; (b) directly bound to the main chain as side groups; or (c) situated on side groups. Type (a) were synthesized by poly-addition of mono- or diamines (or aminoacids) to a compound having two vinyl double bonds activated by adjacent electron attracting groups. These polymers have different chemical functions regularly arranged along the main chain. For (b), the synthesis of polymeric compounds using enamines as monomers is discussed; results of practical interest were obtained by copolymerizing enamines with acrylonitrile to give products which may reach an alternating disposition of the co-units along the chain. In type (c) polymers which are partially stereoregular could also be synthesized, using anionic catalysts at low temperatures.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
