Abstract
A novel method for preparing telechelic 1,4-polybutadiene polymers which have functional groups, such as hydroxy and iodo groups, located at both ends of the polymer chains was described . The chemistry is based on borane-terminated 1,4-polybutadiene intermediates, in which the borane groups can be quantitatively converted to other functional groups under mild reaction conditions. The preparation of borane-terminated 1,4-polybutadiene involves two metathesis reactions which are very effective in providing telechelic polymers with not only a high degree of functionalization but also controllable molecular weight
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