Abstract

Tb-doped SiO2 glasses were synthesized by the spark plasma sintering (SPS) method, and optical and thermally stimulated luminescence (TSL) properties were investigated. The diffuse transmittance spectra of the 0.01, 0.05, and 0.1% Tb-doped SiO2 samples included the absorption due to the 4f-5d transitions of Tb3+ ions. In photoluminescence properties, all the Tb-doped SiO2 samples showed several emission peaks due to the 4f-4f transitions of Tb3+ ions and oxygen deficiency vacancy (ODC). The TSL glow curves indicated the glow peak at 140 °C, and only the emission peaks attributed to the 4f-4f transition of Tb3+ ions were observed in TSL spectra of the 0.01, 0.05, and 0.1% Tb-doped SiO2 samples. The integrated TSL intensity of the 0.1% Tb-doped samples had a proportional relationship in the range of 0.01–1000 mGy. The TSL intensity of the 0.05% Tb-doped glass after 72 h from X-ray irradiation was about 69% with respect to the one immediately after X-ray irradiation. In addition, the 0.05% Tb-doped SiO2 glass could use the multiple time for TSL dosimetry.

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