Synthesis of Ta2O5 by introducing graphene quantum dot with excellent photocatalytic performance for degradation of tetracycline

Abstract

Wide band gap, weak adsorption ability, poor electronic conductivity and insufficient charge transportation limit the applications of Ta2O5 in photodegradation of antibiotics. The paper reports synthesis of Ta2O5 photocatalyst by introducing glycine-functionalized graphene quantum dot (GGQD). The introduction of GGQD effectively prevents the hydrolysis of Ta(V) and finally leads to the formation of small Ta2O5 nanorods. The modification of graphene sheets on the Ta2O5 surface enhances the adsorption towards tetracycline. The presence of Ta4+ self-doped oxygen vacancy narrows the band gap of Ta2O5, optimizes the band position and creates new defect energy level. These improve the light absorption capacity to visible light and promotes the photogenerated charge transfer. The graphene as electron trap suppresses the recombination of photogenerated charge carriers. The graphene as light sensitizer expands the absorption to visible light. The synergy of these multiple structure engineering realizes an excellent photocatalytic performance of Ta2O5 for solar-light driven tetracycline photodegradation. The photodegradation efficiency of 60 min solar-light irradiation is 6.6 times higher, apparent kinetic constant is 19.3 times higher and photocurrent density is 13.4 times over Ta2O5. The study also paves an avenue for construction of metal nanomaterials with desirable photoelectric properties in catalysis, energy storage and conversion and sensing.