Synthesis of superlattice heterostructure of germanium quantum dots in silicon spacer layers and its application in photovoltaic solar cells

Abstract

Superlattice heterostructure of dislocation-free Ge quantum dots buried in Si spacer layers has been synthesized using ultra high vacuum-chemical vapor deposition technique. The heterostructure has been used as active layer in Si solar cells based upon vertical p-i-n junction configuration. Experiment shows that such solar cells exhibit strong repose to infrared radiation in contrast with the negligible response of solar cells with active layers of pure Si having the same thickness. A solar cell with 300 nm thick superlattice is shown to have thermodynamic efficiency of about 11.2%. This is correlated with the rather high quality of the heterostructure used in the present study as judged from photoluminescence spectroscopy and electron microscopy as well as strain and dark current measurements. It is concluded that such type of heterostructure may provide a pathway to develop efficient and cost effective solar cells. • Superlattice heterostructure of Ge quantum dots on Si has been synthesized. • Various techniques have been used to characterize the nanostructures. • The heterostructure has been used as active layer in Si (p-i-n)-type solar cells. • The thermodynamic efficiency of respective solar cell is determined.